ColorMunki Design opens to the main interface however in some cases Mac users have been unable to open the screens to access "Profile My Display" or "Profile My Printer". This is a known issue which seems to be related to the options in the software not being able to access the actual applications themselves. As a workaround navigate to the following:
Mac HD>Library>Application Support>ColorMunki>Design>Tools Once you have the profiling tools open you can either save a copy to your Desktop or lock them in the docking station to have quick access.